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RAYON F.T.C. Definition: A manufactured fiber composed of regenerated
cellulose in which substituents have been replaced not more than
15% of the hydrogens of the hydroxyl group.
Rayon is manufactured from cellulose pulp sheets, usually wood
pulp, but it can be made from other sources such as cotton linters
or other vegetable fibers. The pulp sheets are steeped in a caustic
soda solution which removes undesirable components and also converts
the cellulose to alkali cellulose. The alkali cellulose sheets
are then shredded into "crumb" and aged for a definite
period of time at a constant temperature. The crumb is then loaded
into a dissolver and carbon disulfate added which forms cellulose
xanthate, a bright orange fluffy material. Caustic soda solution
is added to the dissolver which dissolves the xanthate and makes
the thick, orange colored viscose spinning solution. The spinning
solution is then aged until it has the optimum molecular weight
(as measured by viscosity), then it is pumped through a spinneret
into a bath of concentrated sulfuric acid. The acid neutralizes
the alkali caustic viscose solution causing the viscose to precipitate
out, forming the fiber. Byproducts formed in this reaction are
sodium and zinc sulfates which must be continuously removed from
the acid spin bath in a separate purification department.
The wet, soft fiber is then passed over a series of godets or
pulleys where it is stretched to align the cellulose chains and
give the fiber strength, washed and neutralized, sometimes given
a relaxation step to reduce thermal shrinkage of the fiber, coated
with a spin finish lubricant, then dried on steam heated metal
reels and usually given a twist and wound up on spools.
PHYSICAL CHARACTERISTICS OF RAYON
| WATER: |
Swells in water, loses about 40% of its strength
when wet, but regains 100% strength when dry if not allowed
to shrink. Standard regain 11%. |
| HEAT: |
Resists heat well up to 150°C but loses
strength on prolonged exposure and more rapidly at higher
temperatures. Decomposes at 210°C. Rayon will burn readily. |
| ACIDS: |
Attacked by hot dilute and cold concentrated
acids. |
| ALKALIS: |
Resistant. |
| SOLVENTS: |
Resistant to standard solvents. Soluble in
70% sulphuric acid and cuprous ammonium hydroxide. |
| MISC: |
Can be attacked by microbes such as mildew.
Can be chemically made resistant. |
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