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NYLON
F.T.C. Definition: A manufactured fiber in which the fiber forming
substance is any long chain synthetic polymide having recurring
amide groups (-NH-CO-) as an integral part of the polymer chain.
Nylon is manufactured by combining the monomers hexamethylene
diamine and adipic acid in methanol to give nylon salts. The nylon
salt is then dissolved in water and acidified to cause polymerization.
Next, the polymer is washed and dried to prepare it for spinning.
The dried polymer is ground into chips, melted and forced through
a spinnerette. In the next stage, the nylon fibers are heated rapidly
and stretched about 4 times in the original length. This orients
and aligns the molecules which profoundly increases strength. This
also affects modulus and thermal shrinkage. This process describes
the manufacure of nylon 6,6 which is used by Beaver. Other types
of nylons manufactured are 6, nylon 11 and nylon 610. These nylons
vary the monomers used to obtain different physical characteristics.
The actual manufacturing of the different nylons is done in the
same fashion of nylon 6,6.
PHYSICAL CHARACTERISTICS OF NYLON
| WATER: |
Not significantly affected by immersion in
water. Loses some tenacity, but regains it when dry. Standard
moisture regain 4.5%. |
| HEAT: |
Resistant to dry heat. Affected by prolonged
temperatures of 180° C, melts at 250°C. When nylon
burns, it tends to melt away from the flame. Nylon is somewhat
self-extinguishing, but burns in bulk. |
| ACIDS: |
Good resistance. Will disintegrate on heating
with concentrated acids. Soluble in 80% acetic acid at boil.
Soluble in formic acid at room temperature. |
| ALKALIS: |
Resistant. |
| SOLVENTS: |
Not affected by standard hydrocarbons, aromatic
or cholorinated solvents. Soluble in phenosis, especially
meta-cresol. Soluble in di-methyl formamide. |
| MISC: |
Not harmed by microbes. Transparent to UV light.
Nylon is significantly degraded by sunlight but inhibitors
are added during manufacture to reduce this problem. |
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